As a general rule of thumb, you want the suction to the pump to be a larger diameter than the discharge. At worst, equal size. So consider anything that is 1" to be on the suction side of the pump. Anything with 1/2" size on the discharge side of the pump.
A lot of setups have the pressure relief valve going back to the pump suction line, not directly back to the tank or recirc line.
The green valves - As you suspected, one is like the recirc line. The other may be the supply line from the pump to the manifold. I did not see in your list where the 'goes in' barb was for your manifold. I suspect it is a 1/2" barb somewhere.
The two red valves are probably quick closing valves feeding the left and right sides of the boom. If you only had one line back to the boom nozzles, you would have an uneven pressure distribution at your nozzles by the time you got to the last nozzle in the line (and thus uneven flow out of the nozzles.) So run two lines back to the booms (left and right) and try to tee the line at the center of each boom section so as to minimize the number of nozzles in series.
Good luck and have fun with this!
A lot of setups have the pressure relief valve going back to the pump suction line, not directly back to the tank or recirc line.
The green valves - As you suspected, one is like the recirc line. The other may be the supply line from the pump to the manifold. I did not see in your list where the 'goes in' barb was for your manifold. I suspect it is a 1/2" barb somewhere.
The two red valves are probably quick closing valves feeding the left and right sides of the boom. If you only had one line back to the boom nozzles, you would have an uneven pressure distribution at your nozzles by the time you got to the last nozzle in the line (and thus uneven flow out of the nozzles.) So run two lines back to the booms (left and right) and try to tee the line at the center of each boom section so as to minimize the number of nozzles in series.
Good luck and have fun with this!